CORE-LEVEL PHOTOEMISSION AND THE STRUCTURE OF THE SI/SIO2 INTERFACE - A REAPPRAISAL

被引:74
作者
HOLL, MMB [1 ]
LEE, SH [1 ]
MCFEELY, FR [1 ]
机构
[1] IBM CORP,THOMAS J WATSON RES CTR,YORKTOWN HTS,NY 10598
关键词
D O I
10.1063/1.112109
中图分类号
O59 [应用物理学];
学科分类号
摘要
Photoemission spectroscopy of spherosiloxane cluster derived Si/SiO(x) interfaces has allowed the direct assignment of observed spectral features to specific chemical moieties. The implications of these assignments for structural models of the Si/SiO2 interface are explored. Models specifically constructed to be consistent with photoemission data are shown to be incorrect after reanalysis of core-level shifts based on the recently synthesized model systems. A new model for the Si/SiO2 interface is proposed which is consistent with the current understanding of photoemission for Si/SiO(x) interfaces as well as with results from numerous other experiments.
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页码:1097 / 1099
页数:3
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