A HIGHLY SELECTIVE HYDROGEN-DEUTERIUM EXCHANGE IN INDOLIUM HEPTAMETHINE CYANINES

被引:11
作者
LIPOWSKA, M
PATTERSON, SE
PATONAY, G
STREKOWSKI, L
机构
[1] Department of Chemistry, Georgia State University, Atlanta, Georgia
关键词
D O I
10.1002/jhet.5570300503
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chemical shift assignments in H-1 nmr spectra of four tricarbocyanines have been made. Studies by H-1 nmr have shown a rapid acid-catalyzed proton exchange at positions 1',7' and a much slower exchange at positions 3',5' of the heptamethine chain. Base catalysis results in a slow exchange at positions 1',7' only.
引用
收藏
页码:1177 / 1180
页数:4
相关论文
共 14 条
[11]   PROTONENRESONANZUNTERSUCHUNGEN AN CYANINFARBSTOFFEN [J].
SCHEIBE, G ;
SEIFFERT, W ;
WENGENMAYR, H ;
JUTZ, C .
BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1963, 67 (06) :560-570
[12]   SUBSTITUTION-REACTIONS OF A NUCLEOFUGAL GROUP IN HEPTAMETHINE CYANINE DYES - SYNTHESIS OF AN ISOTHIOCYANATO DERIVATIVE FOR LABELING OF PROTEINS WITH A NEAR-INFRARED CHROMOPHORE [J].
STREKOWSKI, L ;
LIPOWSKA, M ;
PATONAY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (17) :4578-4580
[13]   FACILE DERIVATIZATIONS OF HEPTAMETHINE CYANINE DYES [J].
STREKOWSKI, L ;
LIPOWSKA, M ;
PATONAY, G .
SYNTHETIC COMMUNICATIONS, 1992, 22 (17) :2593-2598
[14]   COMPARISON OF COVALENT AND NONCOVALENT LABELING WITH NEAR-INFRARED DYES FOR THE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC DETERMINATION OF HUMAN SERUM-ALBUMIN [J].
WILLIAMS, RJ ;
LIPOWSKA, M ;
PATONAY, G ;
STREKOWSKI, L .
ANALYTICAL CHEMISTRY, 1993, 65 (05) :601-605