SURFACE-ACTIVITY OF A BORON-NITRIDE POWDER - A VIBRATIONAL STUDY

被引：60

作者：

BARATON, MI

MERLE, T

QUINTARD, P

LORENZELLI, V

机构：

[1] LAB SPECTROMETRIE VIBRATIONNELLE,CNRS,URA 320,LMCTS,123 AVE A THOMAS,F-87060 LIMOGES,FRANCE

[2] FAC INGN GENOVA,IST CHIM,I-16129 GENOA,ITALY

来源：

LANGMUIR | 1993年 / 9卷 / 06期

关键词：

D O I：

10.1021/la00030a011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surface of a turbostratic BN powder has been characterized by FT-IR spectrometry. BOH, BNH2, and B2NH species revealing a hydrolyzed surface are identified and the activity of the surface is evidenced by diethyl ether dissociation and acetonitrile polymerization. Other changes in BN surface spectrum by probe-molecule addition are also proposed to be due to an intercalation process.

引用

页码：1486 / 1491

页数：6

共 34 条

[1] CHARACTERIZATION OF FILMS FORMED BY PYROLYSIS OF BORAZINE
ADAMS, AC
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (06) : 1378 - 1379
[2] CHEMICAL-DEPOSITION OF BORON-NITROGEN FILMS
ADAMS, AC
CAPIO, CD
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (02) : 399 - 405
[3] Aita C. R., 1990, SYNTHESIS PROPERTIES, V54-55, P1
[4] SURFACE SPECIES ON A SUBMICRONIC BORON-NITRIDE POWDER - A STARTING FT-IR CHARACTERIZATION
BARATON, MI
MERLE, T
QUINTARD, P
LORENZELLI, V
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1992, 267 : 429 - 434
[5] SURFACE CHARACTERIZATION BY FT-IR SPECTROSCOPY OF AN AEROGEL PRECURSOR TO CORDIERITE
BARATON, MI
MERLEMEJEAN, T
QUINTARD, P
LORENZELLI, V
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (15) : 5930 - 5934
[6] INFRARED SPECTRA OF BORON COMPOUNDS
BELLAMY, LJ
GERRARD, W
LAPPERT, MF
WILLIAMS, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JUN): : 2412 - 2415
[7] INFRARED STUDY OF ALCOHOL ABSORPTION SITES ON ALUMINUM
BENAISSA, M
SAUR, O
LAVALLEY, JC
[J]. MATERIALS CHEMISTRY, 1982, 7 (05): : 699 - 714
[8] Boehm HP, 1983, CATALYSIS SCI TECHNO, P39, DOI DOI 10.1007/978-3-642-93229-8_2
[9] FT-IR STUDY OF THE SURFACE-PROPERTIES OF SILICON-NITRIDE
BUSCA, G
LORENZELLI, V
PORCILE, G
BARATON, MI
QUINTARD, P
MARCHAND, R
[J]. MATERIALS CHEMISTRY AND PHYSICS, 1986, 14 (02) : 123 - 140
[10] FT-IR CHARACTERIZATION OF SILICON-NITRIDE SI3N4 AND SILICON OXYNITRIDE SI2ON2 SURFACES
BUSCA, G
LORENZELLI, V
BARATON, MI
QUINTARD, P
MARCHAND, R
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1986, 143 : 525 - 528

← 1 2 3 4 →