RUTHENIUM DIHYDROGEN COMPLEXES VIA C-H CLEAVAGE IN ALK-1-YNES - CRYSTAL-STRUCTURE OF [RU(H2)(C-EQUIVALENT-TO-CPH)(DIPPE)2][BPH4] [DIPPE = 1,2-BIS(DIISOPROPYLPHOSPHINO)ETHANE]

被引：25

作者：

TENORIO, MJ ^{[1
]}

PUERTA, MC ^{[1
]}

VALERGA, P ^{[1
]}

机构：

[1] UNIV CADIZ,FAC CIENCIAS,DEPT QUIM INORGAN,APTDO 40,E-11510 PUERTO REAL,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 23期

关键词：

D O I：

10.1039/c39930001750

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the monohydride complex [RuH(dippe)2]+ with alk-1-ynes yields the dihydrogen complexes [Ru(H-2)(C=CR)(dippe)2]+ [R = Ph or CO2Me); the X-ray crystal structure of [Ru(H-2)(C=CPh)(dippe)2][BPh4] has been determined, and represents the first structural report of an alkynyl-dihydrogen complex.

引用

页码：1750 / 1751

页数：2

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