RHODIUM(II) ACETATE CATALYZED HYDROSILYLATION OF ENAMIDES AND N-VINYLUREAS LEADING TO 1-(TRIALKYLSILYL)ALKYLAMINE DERIVATIVES

被引：23

作者：

MURAI, T

ODA, T

KIMURA, F

ONISHI, H

KANDA, T

KATO, S

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The[Rh-2(OAc)(4)] catalysed hydrosilylation of enamides and N-vinylureas with dimethylphenylsilane proceeds smoothly in a regio- and site-selective manner to give 1-(trailkylsilyl)alkylamine derivatives in good to high yields.

引用

页码：2143 / 2144

页数：2

共 18 条

[1] COMPLEX-INDUCED PROXIMITY EFFECTS - ENANTIOSELECTIVE SYNTHESES BASED ON ASYMMETRIC DEPROTONATIONS OF N-BOC-PYRROLIDINES [J].

BEAK, P ;

KERRICK, ST ;

WU, SD ;

CHU, JX .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3231-3239

[2] INTERCEPTION AND CHARACTERIZATION OF A HYDRIDOALKYLRHODIUM INTERMEDIATE IN A HOMOGENEOUS CATALYTIC-HYDROGENATION REACTION [J].

CHAN, ASC ;

HALPERN, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :838-840

[3] HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) AS AN EFFECTIVE CATALYST FOR THE REGIOSPECIFIC HYDROSILATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

CHAN, TH ;

ZHENG, GZ .

TETRAHEDRON LETTERS, 1993, 34 (19) :3095-3098

[4]

HIYAMA T, 1991, COMPREHENSIVE ORGANI, V8, P763

[5] REGIOSELECTIVE INCORPORATION OF CO INTO ENAMINES BY RHODIUM-CATALYZED REACTION WITH A HYDROSILANE AND CO [J].

IKEDA, S ;

CHATANI, N ;

KAJIKAWA, Y ;

OHE, K ;

MURAI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (01) :2-4

[6] SYNTHESIS OF (AMINOMETHYL)SILANES WITH THE USE OF AN EASILY CLEAVABLE CARBON-SILICON BOND [J].

LABRECQUE, D ;

NWE, KT ;

CHAN, TH .

ORGANOMETALLICS, 1994, 13 (01) :332-335

[7]

LEE YJ, 1993, TETRAHEDRON LETT, V34, P5855

[8] STEREOSELECTIVE SYNTHESIS OF N,N-DIVINYLUREAS BY DIIRON ENNEACARBONYL-CATALYZED ISOMERIZATION OF N,N-DIALLYLIC OR N-ALLYLIC N-VINYLUREAS [J].

MURAI, T ;

KASAI, Y ;

ISHIHARA, H ;

KATO, S .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (20) :5542-5545

[9] NOVEL GENERATION OF AZOMETHINE YLIDE FROM N-(ALPHA-SILYLBENZYL)AMIDE BY SILICON SHIFT - AN EQUIVALENT OF NITRILE YLIDE [J].

OHNO, M ;

KOMATSU, M ;

MIYATA, H ;

OHSHIRO, Y .

TETRAHEDRON LETTERS, 1991, 32 (41) :5813-5816

[10] REDUCTION OF CARBONYL-COMPOUNDS VIA HYDROSILYLATION .4. HIGHLY REGIOSELECTIVE REDUCTIONS OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

OJIMA, I ;

KOGURE, T .

ORGANOMETALLICS, 1982, 1 (10) :1390-1399

← 1 2 →