NEW LIGANDS FOR ASYMMETRIC PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS - X-RAY CRYSTAL-STRUCTURES OF 2 ENANTIOMERICALLY PURE DIHYDROBENZAZAPHOSPHOLE-BORANE COMPLEXES

被引：25

作者：

BRENCHLEY, G

FEDOULOFF, M

MAHON, MF

MOLLOY, KC

WILLS, M

机构：

[1] UNIV BATH,SCH CHEM,XRAY CRYSTALLOG UNIT,BATH BA2 7AY,AVON,ENGLAND

[2] SMITHKLINE BEECHAM PHARMACEUT,HARLOW CM19 5AD,ESSEX,ENGLAND

来源：

TETRAHEDRON | 1995年 / 51卷 / 38期

关键词：

D O I：

10.1016/0040-4020(95)00621-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis, application and X-ray crystal structures of two enantiomerically pure dihydrobenzazaphosphole-borane complexes, precursors of ligands for highly enantioselective palladium catalysed allylic substitution reactions, are described. The structures provide the basis for an explanation of the observed stereochemistry.

引用

页码：10581 / 10592

页数：12

共 49 条

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