AXIALLY CHIRAL AMIDINIUM IONS WITH A BIARYL SKELETON - A NEW CLASS OF STRUCTURE IN HOST-GUEST CHEMISTRY

被引：8

作者：

LEHR, S

SCHUTZ, K

BAUCH, M

GOBEL, MW

机构：

[1] Institut Für Organische Chemie, Universität Frankfurt, D-60439

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As receptors and catalysts in host–guest chemistry the title compounds can be recommended. The stereoselective ring closure of aminonitriles is the key to the synthesis of this new type of axially chiral cation. The chiral center of the side chain, which stems from an α‐amino acid, transfers its absolute configuration to the biaryl skeleton. This principle provides access to a wide variety of target structures such as 1. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：984 / 986

页数：3

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