FORMATION OF INTERWOVEN OR PARTIALLY INTERWOVEN METALLOMACROCYCLIC NETWORKS IN COPPER(II) OR ZINC(II) COMPLEXES WITH N,N'-P-PHENYLENEDIMETHYLENEBIS(PYRIDIN-4-ONE)

被引：19

作者：

GOODGAME, DML

MENZER, S

SMITH, AM

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001975

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray structural studies show that in the compounds [CU2(p-XBP4)(3)(NO3)(2)](NO3)(2) . 2H(2)O and [Zn-2(p-XBP4)(4)](BF4)(4) . 4H(2)O [pXBP4 = N,N'-p-phenylenedimethylenebis(pyridin-4-one)] pyridone oxygen atoms bridge pairs of metal ions to form M(2)O(2) units which, in turn, are linked by p-XBP4 bridges to produce complex arrays of, for Zn, 34- and 38-membered rings or, for Cu, 68-membered rings 'threaded' by interwoven p-XBP4 strands.

引用

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页码：1975 / 1977

页数：3

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