THE THERMAL-DEGRADATION OF ACRYLONITRILE-BUTADIENE-STYRENE TERPOLYMER GRAFTED WITH METHACRYLIC-ACID

被引：25

作者：

SUZUKI, M ^{[1
]}

WILKIE, CA ^{[1
]}

机构：

[1] JAPAN SYNTH RUBBER CO LTD,YOKKAICHI,MIE 510,JAPAN

来源：

POLYMER DEGRADATION AND STABILITY | 1995年 / 47卷 / 02期

关键词：

D O I：

10.1016/0141-3910(94)00113-M

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Grafting of methacrylic acid, and especially the conversion of the acid to the sodium salt, has a significant effect on the degradation of acrylonitrile-butadiene-styrene (ABS) terpolymer. The amount of non-volatile residue obtained at 800 degrees C is greatly increased after grafting. Cone calorimetry indicates significant improvement in all parameters. It has been determined by TGA-FTIR that the degradation of all portions of the terpolymer commences at higher temperatures than unmodified ABS, due to the effect of the char layer formed on the surface of the terpolymer.

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页码：223 / 228

页数：6

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共 20 条

[1] THE INTERACTION OF POLY(METHYL METHACRYLATE) AND CHROMIUM CHLORIDE - TRANSFER OF METHYL-GROUPS FROM THE ESTER TO THE MAIN CHAIN [J].

BEER, RS ;

WILKIE, CA ;

MITTLEMAN, ML .

JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 46 (06) :1095-1102

[2] INHIBITION BY RED PHOSPHORUS OF UNIMOLECULAR THERMAL CHAIN-SCISSION IN POLY(METHYL METHACRYLATE) - INVESTIGATION BY NMR, FT-IR AND LASER DESORPTION FOURIER-TRANSFORM MASS-SPECTROSCOPY [J].

BROWN, CE ;

WILKIE, CA ;

SMUKALLA, J ;

CODY, RB ;

KINSINGER, JA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1986, 24 (06) :1297-1311

[3] THE EFFECT OF SOME TRANSITION-METAL CHLORIDES ON THE THERMAL-DEGRADATION OF POLY(METHYL METHACRYLATE) - A STUDY USING TGA-FTIR SPECTROMETRY [J].

CHANDRASIRI, JA ;

ROBERTS, DE ;

WILKIE, CA .

POLYMER DEGRADATION AND STABILITY, 1994, 45 (01) :97-101

[4] THERMAL-DEGRADATION OF POLY(METHYL METHACRYLATE) IN THE PRESENCE OF TIN-(IV) CHLORIDE AND TETRAPHENYLTIN [J].

CHANDRASIRI, JA ;

WILKIE, CA .

POLYMER DEGRADATION AND STABILITY, 1994, 45 (01) :91-96

[5] THE THERMOLYSIS OF POLY(METHYL METHACRYLATE) IN THE PRESENCE OF PHENYLTIN CHLORIDES PH(X)SNCL(4-X) (X=1-3) [J].

CHANDRASIRI, JA ;

WILKIE, CA .

POLYMER DEGRADATION AND STABILITY, 1994, 45 (01) :83-89

[6] THERMAL-DEGRADATION OF DIPHENYL DISULFIDE AND A BLEND OF DIPHENYL DISULFIDE WITH POLY(METHYL METHACRYLATE) [J].

CHANDRASIRI, JA ;

WILKIE, CA .

POLYMER DEGRADATION AND STABILITY, 1994, 46 (02) :275-284

[7] SURFACE MODIFICATION OF POLYMERS .1. GRAFTING INITIATED BY PHOTO-GENERATED HYDROPEROXIDES [J].

GEUSKENS, G ;

KANDA, MN .

EUROPEAN POLYMER JOURNAL, 1991, 27 (09) :877-879

[8] SURFACE MODIFICATION OF POLYMERS .2. PHOTOOXIDATION OF SBS CONTAINING ANTHRACENE AND GRAFTING INITIATED BY PHOTO-GENERATED HYDROPEROXIDES [J].

GEUSKENS, G ;

THIRIAUX, P .

EUROPEAN POLYMER JOURNAL, 1993, 29 (2-3) :351-355

[9] PREPARATION AND THERMAL-DEGRADATION OF COPOLYMERS OF 2-SULFOETHYL METHACRYLATE AND METHYL-METHACRYLATE [J].

HURLEY, SL ;

MITTLEMAN, ML ;

WILKIE, CA .

POLYMER DEGRADATION AND STABILITY, 1993, 39 (03) :345-354

[10] THERMAL-DEGRADATION OF AMMONIUM POLYMETHACRYLATE AND POLYMETHACRYLAMIDE [J].

MCNEILL, IC ;

ZULFIQAR, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (10) :2465-2474