AN UNPRECEDENTED TRIDENTATE MODE OF COORDINATION OF A BINAP LIGAND - SYNTHESIS AND CRYSTAL-STRUCTURES OF [RU(ETA-5-C5H5)((R)-(BINAP))]+CF3SO3- AND RU(ETA-5-C5H5)((R)-(BINAP))I

被引：41

作者：

PATHAK, DD ^{[1
]}

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

KING, PJ ^{[1
]}

WHITE, C ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 479卷 / 1-2期

关键词：

RUTHENIUM; CRYSTAL STRUCTURE; POLYDENTATE; TRIFLATE; CYCLOPENTADIENYL; BINAP;

D O I：

10.1016/0022-328X(94)84115-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and crystal structures of the title compounds are reported. The complex [Ru(eta5-C5H5){(R)-(BINAP)}]+CF3SO- is of particular interest in that it contains a tridentate BINAP ligand co-ordinated to the ruthenium through eta2-bonding to one of the naphthyl rings as well as through both phosphorus atoms. The possible implications of this type of bonding are discussed.

引用

页码：237 / 245

页数：9

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