TETRATHIAFULVALENE AS A TRIGGER FOR SEQUENTIAL RADICAL TRANSLOCATION AND FUNCTIONALIZATION

被引：14

作者：

BEGLEY, MJ ^{[1
]}

MURPHY, JA ^{[1
]}

ROOME, SJ ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)78470-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl diazonium salts react with tetrathiafulvalene to generate aryl radicals which undergo intramolecular hydrogen atom abstractions; the radicals which result lend to (a) oxidised product or (b) undergo an unprecedented carbon-carbon bond formation with the radical-cation of tetrathiafulvalene.

引用

页码：8679 / 8682

页数：4

共 21 条

[1]

BARTON DHR, 1968, PURE APPL CHEM, V16, P1

[2] A NEW 4-SUBSTITUTED-2-CYCLOHEXENONE SYNTHESIS [J].