SYNTHESIS OF CROSS-LINKED PLATINUM METAL CONTAINING POLYYNE POLYMERS

被引：41

作者：

KHAN, MS ^{[1
]}

SCHWARTZ, DJ ^{[1
]}

PASHA, NA ^{[1
]}

KAKKAR, AK ^{[1
]}

LIN, B ^{[1
]}

RAITHBY, PR ^{[1
]}

LEWIS, J ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 616卷 / 10期

关键词：

CROSS-LINKED; RIGID-ROD; SIGMA-ACETYLIDE; PI-CONJUGATION; ELECTRONIC PROPERTIES; POLYYNE COPOLYMER;

D O I：

10.1002/zaac.19926161018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu3)2Cl2 (2) with stoichiometric amounts of 1,3,5-triethynylbenzene, [1,3,5-(H-C=C-)3C6H3 (3) yields monomeric, [1,3,5-Cl(PnBu3)2Pt-C=C-)3C6H3] (4), [1,3,5-(Cl(ASnBu3)2Pt-C=C-)3C6H3] (5) or polymeric, {1,3,5-[(PnBu3)2Pt-C=C-]3C6H3-}n (6), {1,3,5-[(AsnBu3)2Pt-C=C-]3C6H3-}n (7) complexes. Treatment of (1) with (3) and 2,5-diethynyl-p-xylene, H-C=C-C6H2(CH3)2-C=C-H (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

引用

页码：121 / 124

页数：4

共 15 条

[1] FACILE SYNTHESIS OF ETHYNYLATED BENZOIC-ACID DERIVATIVES AND AROMATIC-COMPOUNDS VIA ETHYNYLTRIMETHYLSILANE
AUSTIN, WB
BILOW, N
KELLEGHAN, WJ
LAU, KSY
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (11) : 2280 - 2286
[2] BLAU WJ, 1991, J MATER CHEM, V1, P235
[3] SYNTHESIS OF LINKED METAL ACETYLIDE COMPLEXES FOR NONLINEAR OPTICS
DAVIES, SJ
JOHNSON, BFG
LEWIS, J
KHAN, MS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 401 (03) : C43 - C45
[4] SYNTHESIS OF MONOMERIC AND OLIGOMERIC BIS(ACETYLIDE) COMPLEXES OF PLATINUM AND RHODIUM
DAVIES, SJ
JOHNSON, BFG
KHAN, MS
LEWIS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) : 187 - 188
[5] SYNTHESIS OF MONONUCLEAR AND OLIGOMERIC RUTHENIUM(II) ACETYLIDES
DAVIES, SJ
JOHNSON, BFG
LEWIS, J
RAITHBY, PR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 414 (02) : C51 - C53
[6] Solid state multinuclear NMR study of sigma-acetylide complexes of platinum, trans-[ClPt(P-n Bu-3)(2)-C C-p-C6H4-C C-Pt(P-n Bu-3)(2)Cl] and trans-[-Pt(P-n Bu-3)(2)-C C-p-C6H4-C C-](n)
Duer, Melinda J.
Khan, Muhammad S.
Kakkar, Ashok K.
[J]. SOLID STATE NUCLEAR MAGNETIC RESONANCE, 1992, 1 (01) : 13 - 16
[7] HAGIHARA N, 1980, ADV POLYM SCI, V41, P149
[8] SYNTHESIS AND OPTICAL SPECTROSCOPY OF PLATINUM-METAL-CONTAINING DI-ACETYLENIC AND TRI-ACETYLENIC POLYMERS
JOHNSON, BFG
KAKKAR, AK
KHAN, MS
LEWIS, J
DRAY, AE
FRIEND, RH
WITTMANN, F
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (03) : 485 - 486
[9] SYNTHESIS OF NOVEL RIGID ROD IRON METAL CONTAINING POLYYNE POLYMERS
JOHNSON, BFG
KAKKAR, AK
KHAN, MS
LEWIS, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 409 (03) : C12 - C14
[10] Kaufman G. B., 1963, INORG SYNTH, V7, P248

← 1 2 →