SYNTHESIS OF BOTH AXIALLY CHIRAL BIARYLS BY CROSS-COUPLING OF (ARENE)CHROMIUM COMPLEXES WITH NAPHTHYLBORONIC ACIDS AND SUBSEQUENT AXIAL ISOMERIZATION

被引：32

作者：

WATANABE, T ^{[1
]}

KAMIKAWA, K ^{[1
]}

UEMURA, M ^{[1
]}

机构：

[1] OSAKA CITY UNIV,FAC SCI,OSAKA 558,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 37期

关键词：

D O I：

10.1016/00404-0399(50)1354K-

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diastereomerically axial naphthyl(eta(6)-phenyl)Cr(CO)3 complexes were prepared by cross-coupling of (arene)chromium complexes with naphthylboronic acids and subsequent axial isomerization by refluxing of the coupling products in a higher boiling point solvent.

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页码：6695 / 6698

页数：4

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