HIGHLY DIASTEREOSELECTIVE, ENANTIOSELECTIVE CYCLIZATION OF SYMMETRICAL 3,4-DISUBSTITUTED 4-PENTENAL USING CHIRAL RHODIUM(I)-COMPLEX

被引：40

作者：

WU, XM ^{[1
]}

FUNAKOSHI, K ^{[1
]}

SAKAI, K ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC PHARMACEUT SCI,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期

关键词：

ENANTIOSELECTIVE CYCLIZATION; CATIONIC RHODIUM; NEUTRAL RHODIUM; CHIRAL LIGAND; BINAP; 3,4-DISUBSTITUTED CYCLOPENTANONE; DIASTEREOSELECTIVE CYCLIZATION; 3-ISOPROPENYL-4-METHYL-4-PENTEN-1-AL;

D O I：

10.1016/S0040-4039(00)73816-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Concurrent introduction of two chiral centers at 3,4-positions of cyclopentanone from symmetrical 1 was achieved in diastereoselective and enantioselective fashion by combination of BINAP and cationic Rh(I)(or neutral).

引用

页码：5927 / 5930

页数：4

共 10 条

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