METHYL 1,2-DIHYDROFULLERENECARBOXYLATE

被引：55

作者：

WIN, WW

KAO, M

EIERMANN, M

MCNAMARA, JJ

WUDL, F

POLE, DL

KASSAM, K

WARKENTIN, J

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,DEPT PHYS,SANTA BARBARA,CA 93106

[2] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ON,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 20期

关键词：

D O I：

10.1021/jo00099a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the preparation of the title compound, the first fullerenecarboxylic acid derivative, by hydrolysis of dimethoxymethanofullerene. The latter was prepared from dimethoxycarbene and C-60. The title ester is quite unreactive; conventional saponification methods, including sulfuric acid, trimethylsilyl iodide, and boron tribromide, failed to transform the ester to acid. A special phase-transfer-catalysis procedure effected hydrolysis but the only characterizable product was buckminsterfullerene (C-60).

引用

页码：5871 / 5876

页数：6

共 29 条

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