AN UNUSUALLY STRICT PRODUCT PARTITION OF AN EXCITED DIAZIRINE CARBENE SYSTEM

被引：22

作者：

MOSS, RA

LIU, WG

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 21期

关键词：

D O I：

10.1039/c39930001597

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of 3-tert-butyl-3-chlorodiazirine produces 2-chloro-3-methyl-but-2-ene and 2,2-dimethyl-1-chlorocyclopropane; the former stems from 1,2-methyl migration and nitrogen loss in the excited state diazirine, whilst the latter is a product of 1,3-CH insertion in the tert-butylchlorocarbene derived from the diazirine.

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页码：1597 / 1599

页数：3

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