OPTICALLY-ACTIVE BETA-KETOIMINATO MANGANESE(III) COMPLEXES AS EFFICIENT CATALYSTS IN ENANTIOSELECTIVE AEROBIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS

被引：28

作者：

NAGATA, T

IMAGAWA, K

YAMADA, T

MUKAIYAMA, T

机构：

[1] MITSUI PETROCHEM IND CO LTD,BASIC RES LABS ORGAN SYNTH,SODEGAURA,CHIBA 29902,JAPAN

[2] SCI UNIV TOKYO,FAC SCI,DEPT APPL CHEM,SHINJUKU KU,TOKYO 162,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1994年 / 220卷 / 1-2期

关键词：

CATALYSIS; ENANTIOSELECTIVITY; EPOXIDATION; MANGANESE COMPLEXES; X-RAY DIFFRACTION; OXIDATION; ASYMMETRIC SYNTHESIS; MOLECULAR OXYGEN;

D O I：

10.1016/0020-1693(94)03880-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel manganese(III) complex having an optically active N,N'-ethylenebis-beta-ketoimine ligand was prepared and characterized crystallographically. The manganese(III) complexes behave as effective catalysts in enantioselective epoxidation of unfunctionalized olefins by combined use of molecular oxygen, an oxidant, and pivalaldehyde, a reductant. Dihydronaphthalene derivatives were converted into the corresponding optically active epoxides with good to high enantioselectivities.

引用

收藏

页码：283 / 287

页数：5

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