OUTDIFFUSION AND SUBSEQUENT DESORPTION OF VOLATILE SIO MOLECULES DURING ANNEALING OF THICK SIO2-FILMS IN VACUUM

被引:28
作者
TAKAKUWA, Y
NIHEI, M
MIYAMOTO, N
机构
[1] Research Institute of Electrical Communication, Tohoku University, Aoba-ku, Sendai, 980
[2] Fujitsu Laboratories Ltd., Wakamiya, Atsugi, 243-01, Morinosato
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1993年 / 32卷 / 4A期
关键词
SIO2; SUBOXIDE; VOLATILE SIO; DIFFUSION; DESORPTION; ANGLE-RESOLVED XPS;
D O I
10.1143/JJAP.32.L480
中图分类号
O59 [应用物理学];
学科分类号
摘要
The depth profile of so-called suboxides in the surface region for 1000-angstrom-thick SiO2 films annealed in vacuum at 800-degrees-C was measured by angle-resolved X-ray photoelectron spectroscopy. It was found that the amount of suboxide distributed under the surface increases rapidly and almost saturates with annealing time, while the change in the amount of suboxide present on the surface is very small and increases gradually with annealing time. This indicates that very fast outdiffusion of SiO molecules through thick SiO2 films takes place at as low as 800-degrees-C, leading to desorption from the SiO2 surface.
引用
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页码:L480 / L483
页数:4
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