First metal azide complex with isonicotinate as a bridging ligand showing new net topology: Hydrothermal synthesis, structure, and magnetic properties

被引:127
作者
Liu, FC
Zeng, YF
Jiao, J
Bu, XH [1 ]
Ribas, J
Batten, SR
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
关键词
D O I
10.1021/ic051896h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new 3D azido-bridged coordination polymer, [CO1.5(N-3)(OH)(Isonic)](n) (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.
引用
收藏
页码:2776 / 2778
页数:3
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