Iron-catalyzed C-C bond formation by direct functionalization of C-H bonds adjacent to heteroatoms

被引：281

作者：

Li, Zhiping ^{[1
]}

Yu, Rong ^{[1
]}

Li, Haijun ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 39期

关键词：

C-H activation; cross-coupling; heterocycles; iron; peroxides;

D O I：

10.1002/anie.200802215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron/oxidant can do: Heteroatom-containing molecules are abundant in natural products, pharmaceuticals, and materials. It is highly desirable to synthesize these molecules and their derivatives by direct C-H functionalization. The novel title reaction provides a simple and efficient method to construct such molecules by using 1,3-dicarbonyl compounds (see scheme). (Chemical Equation Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7497 / 7500

页数：4

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