Self-assembled bidentate ligands for Ru-catalyzed anti-Markovnikov hydration of terminal alkynes

被引：159

作者：

Chevallier, F ^{[1
]}

Breit, B ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

alkynes; homogeneous catalysis; hydrogen bonding; ruthenium; self-assembly;

D O I：

10.1002/anie.200503826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) In pairs: Bidentate ligands are generated by the self-assembly of monodentate ligands through complementary hydrogen bonding. A ruthenium complex bearing such self-assembled heterodimeric ligands is used as the catalyst in the regioselective hydration of terminal alkynes. FG = functional group, Piv = pivaloyl. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1599 / 1602

页数：4

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