Air-assisted high-performance field-effect transistor with thin films of picene

被引:224
作者
Okamoto, Hideki [1 ]
Kawasaki, Naoko [2 ]
Kaji, Yumiko [2 ]
Kubozono, Yoshihiro [2 ]
Fujiwara, Akihiko [3 ]
Yamaji, Minoru [4 ]
机构
[1] Okayama Univ, Div Chem & Biochem, Okayama 7008530, Japan
[2] Okayama Univ, Surface Sci Res Lab, Okayama 7008530, Japan
[3] Japan Adv Inst Sci & Technol, Ishikawa 9231292, Japan
[4] Gunma Univ, Dept Chem & Chem Biol, Kiryu, Gunma 3768515, Japan
关键词
D O I
10.1021/ja803291a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A field-effect transistor (FET) with thin films of picene has been fabricated on SiO2 gate dielectric. The FET showed p-channel enhancement-type FET characteristics with the field-effect mobility, mu, of 1.1 cm(2) V-1 s(-1) and the on-off ratio of >10(5). This excellent device performance was realized under atmospheric conditions. The p increased with an increase in temperature, and the FET performance was improved by exposure to air or O-2 for a long time. This result implies that this device is an air (O-2)-assisted FET. The FET characteristics are discussed on the basis of structural topography and the energy diagram of picene thin films.
引用
收藏
页码:10470 / +
页数:3
相关论文
共 19 条
[11]   High field-effect mobility oligofluorene derivatives with high environmental stability [J].
Meng, H ;
Bao, ZN ;
Lovinger, AJ ;
Wang, BC ;
Mujsce, AM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :9214-9215
[12]   2,6-bis[2-(4-pentylphenyl)vinyl]anthracene: A stable and high charge mobility organic semiconductor with densely packed crystal structure [J].
Meng, Hong ;
Sun, Fangping ;
Goldfinger, Marc B. ;
Gao, Feng ;
Londono, David J. ;
Marshal, Will J. ;
Blackman, Greg S. ;
Dobbs, Kerwin D. ;
Keys, Dalen E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (29) :9304-9305
[13]   p-channel organic semiconductors based on hybrid acene-thiophene molecules for thin-film transistor applications [J].
Merlo, JA ;
Newman, CR ;
Gerlach, CP ;
Kelley, TW ;
Muyres, DV ;
Fritz, SE ;
Toney, MF ;
Frisbie, CD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) :3997-4009
[14]   Temperature-independent transport in high-mobility pentacene transistors [J].
Nelson, SF ;
Lin, YY ;
Gundlach, DJ ;
Jackson, TN .
APPLIED PHYSICS LETTERS, 1998, 72 (15) :1854-1856
[15]   Intrinsic charge transport on the surface of organic semiconductors [J].
Podzorov, V ;
Menard, E ;
Borissov, A ;
Kiryukhin, V ;
Rogers, JA ;
Gershenson, ME .
PHYSICAL REVIEW LETTERS, 2004, 93 (08) :086602-1
[16]   Decyl-end-capped thiophene-phenylene oligomers as organic semiconducting materials with improved oxidation stability [J].
Ponomarenko, SA ;
Kirchmeyer, S ;
Elschner, A ;
Alpatova, NM ;
Halik, M ;
Klauk, H ;
Zschieschang, U ;
Schmid, G .
CHEMISTRY OF MATERIALS, 2006, 18 (02) :579-586
[17]   Very high-mobility organic single-crystal transistors with in-crystal conduction channels [J].
Takeya, J. ;
Yamagishi, M. ;
Tominari, Y. ;
Hirahara, R. ;
Nakazawa, Y. ;
Nishikawa, T. ;
Kawase, T. ;
Shimoda, T. ;
Ogawa, S. .
APPLIED PHYSICS LETTERS, 2007, 90 (10)
[18]   Growth and electronic transport in 9,10-diphenylanthracene single crystals - An organic semiconductor of high electron and hole mobility [J].
Tripathi, Ashutosh Kumar ;
Heinrich, Michael ;
Siegrist, Theo ;
Pflaum, Jens .
ADVANCED MATERIALS, 2007, 19 (16) :2097-+
[19]   Electron and ambipolar transport in organic field-effect transistors [J].
Zaumseil, Jana ;
Sirringhaus, Henning .
CHEMICAL REVIEWS, 2007, 107 (04) :1296-1323