Homogeneous catalysis with transition metal complexes containing sulfur ligands

被引：201

作者：

Bayón, JC ^{[1
]}

Claver, C

Masdeu-Bultó, AM

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08913, Spain

[2] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 193-5卷

关键词：

homogenous catalysis; sulfur ligands; transition metals;

D O I：

10.1016/S0010-8545(99)00169-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition metal complexes with sulfur ligands are active catalysts in a considerable number of homogeneous reactions, although they have been less investigated than complexes with other donor atoms. We review the application of complexes containing sulfur ligands in hydrogenation, hydrogen transfer, isomerization, hydrosilylation, carbonylation, hydroformylation, polymerization, Heck reaction, allylic alkylation, Grignard cross-coupling, conjugate addition and oxidation with O-2. The use of different types of sulfur ligands and the characteristics of the coordination complexes are described together with the results of the catalytic reactions. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：73 / 145

页数：73

共 269 条

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