Controllable growth of ZnO nanowhiskers by a simple solution route

被引:41
作者
Li, Ping [1 ]
Liu, Hui [1 ]
Xu, Fang-xiang [1 ]
Wei, Yu [1 ]
机构
[1] Hebei Normal Univ, Sch Chem & Mat Sci, Prov Key Lab Inorgan Nanomat, Shijiazhuang 050016, Hebei, Peoples R China
关键词
ZnO nanowhiskers; Hydrothermal; Synthesis; Growth mechanism;
D O I
10.1016/j.matchemphys.2008.05.065
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
One-dimensional (1D) needle-like ZnO nanowhiskers have been grown directly from aqueous solution Received 26 February 2008 containing Zn(OH)(4)(2-) ions which is produced by zinc chloride and sodium hydroxide, in the presence of sodium dodecyl sulfate (SDS). Through the improved novel approach, uniform ZnO nanowhiskers with diameters ranging from 80 to 120 nm and an average length of about 4 mu m (aspect ratio similar to 40:1) were successfully prepared at a low hydrothermal temperature (85 degrees C) with a short reaction time (5 h). The nanowhiskers exhibit a perfect single crystalline wurtzite structure with [0 0 0 1] as the growth orientation. The growth mechanism, as well as the controllable factors on the crystal size and shape, is also discussed in detail. (c) 2008 Published by Elsevier B.V.
引用
收藏
页码:393 / 397
页数:5
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