A simple and efficient iron-catalyzed intramolecular hydroamination of unactivated olefins

被引：195

作者：

Komeyama, Kimihiro ^{[1
]}

Morimoto, Takayuki ^{[1
]}

Takaki, Ken ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Chem & Chem Engn, Higashihiroshima 7398527, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期

关键词：

alkenes; homogeneous catalysis; hydroamination; iron; nitrogen heterocycles;

D O I：

10.1002/anie.200503789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A new catalytic activity of iron salts for intramolecular hydroamination is revealed. A number of aminoolefins underwent the reaction under mild conditions to form the corresponding pyrrolidine derivatives in good yield. The reaction displayed good functional-group compatibility and resistance to air and moisture. (Ts = e-toluenesulfonyl). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2938 / 2941

页数：4

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