Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

被引：44

作者：

Hirai, Kenji ^{[2
]}

Furukawa, Shuhei ^{[1
,3
]}

Kondo, Mio ^{[1
,3
]}

Meilikhov, Mikhail ^{[1
,3
]}

Sakata, Yoko ^{[1
,3
]}

Sakata, Osami ^{[4
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[4] Natl Inst Mat Sci, Synchrotron Xray Stn SPring 8, Sayo, Hyogo 6795198, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 52期

关键词：

METAL-ORGANIC FRAMEWORK; SEPARATION; ADSORPTION; ANTHRACENE; COMPLEXES; DESIGN; AMINES;

D O I：

10.1039/c2cc31421e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

引用

页码：6472 / 6474

页数：3

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