Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon-carbon bond forming reactions

被引：892

作者：

Terada, Masahiro ^{[1
]}

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Med, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 35期

关键词：

D O I：

10.1039/b807577h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binaphthol-derived monophosphoric acids have been designed as novel chiral Bronsted-acid catalysts. The chiral phosphoric acids thus developed function as efficient enantioselective catalysts for a variety of organic transformations, especially for carbon-carbon bond forming reactions.

引用

页码：4097 / 4112

页数：16

共 128 条

[81] Asymmetric bronsted acid catalysis: Enantioselective nucleophilic substitutions and 1,4-additions [J].

Rueping, Magnus ;

Nachtsheim, Boris J. ;

Moreth, Stefan A. ;

Bolte, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :593-596

[82] Organocatalytic enantioselective reduction of Pyridines [J].

Rueping, Magnus ;

Antonchick, Andrey P. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (24) :4562-4565

[83] Chiral Bronsted acids in the catalytic asymmetric Nazarov cyclization - The first enantioselective organocatalytic electrocyclic reaction [J].

Rueping, Magnus ;

Ieawsuwan, Winai ;

Antonchick, Andrey P. ;

Nachtsheim, Boris J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (12) :2097-2100

[84] Remarkably low catalyst loading in Bronsted acid catalyzed transfer hydrogenations: Enantioselective reduction of benzoxazines, benzothiazines, and benzoxazinones [J].

Rueping, Magnus ;

Antonchick, Andrey P. ;

Theissmann, Thomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (40) :6751-6755

[85] Asymmetric construction of quaternary stereocenters by direct organocatalytic amination of α-substituted α-cyanoacetates and β-dicarbonyl compounds [J].

Saaby, S ;

Bella, M ;

Jorgensen, KA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (26) :8120-8121

[86] Metal-free organocatalysis through explicit hydrogen bonding interactions [J].

Schreiner, PR .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :289-296

[87] Axially chiral amidinium ions as inducers of enantioselectivity in Diels-Alder reactions [J].

Schuster, T ;

Bauch, M ;

Dürner, G ;

Göbel, MW .

ORGANIC LETTERS, 2000, 2 (02) :179-181

[88] Catalytic asymmetric Pictet-Spengler reaction [J].

Seayad, J ;

Seayad, AM ;

List, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) :1086-1087

[89]

SEEBACH D, 1985, MODERN SYNTHETIC MET, V3, P217

[90] Recent progress in asymmetric two-center catalysis [J].

Shibasaki, M ;

Kanai, M ;

Funabashi, K .

CHEMICAL COMMUNICATIONS, 2002, (18) :1989-1999

← 4 5 6 7 8 9 10 11 12 13 →