Uniform one-dimensional arrays of tunable gold nanoparticles with tunable interparticle distances

被引:46
作者
Corbierre, Muriel K.
Beerens, Jean
Beauvais, Jacques
Lennox, R. Bruce
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
[2] McGill Univ, Ctr Self Assembled Chem Struct, Montreal, PQ H3A 2K6, Canada
[3] Univ Sherbrooke, Dept Genie Elect & Informat, Sherbrooke, PQ J1K 2R1, Canada
关键词
D O I
10.1021/cm060235v
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation of uniform one-dimensional arrays of tunable gold nanoparticles with tunable interparticle distances was investigated. The AU(I)-thiolate complexes were synthesized using readily available precursors. These compounds were designed to be soluble materials that readily spread on to surfaces, due to the bulky thiol ligands used. The X-ray photoelectron microscopy (XPS) analysis of a large 2-D array of the gold nanoparticles reveals that they are composed solely of metallic gold. The interparticle distance and the patterns composed of nanoparticles are readily tunable on a given substrate by varying electron beam parameters. It is anticipated that this method is a versatile technique that can be applied to many other organometallic systems.
引用
收藏
页码:2628 / 2631
页数:4
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