An electrochemical cell coupled with disposable screen-printed electrodes for use in flow injection analysis

被引:27
作者
Hsu, CT
Chung, HH
Lyuu, HJ
Tsai, DM
Kumar, AS
Zen, JM [1 ]
机构
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan
[2] Zensor Res & Dev, Taichung 421, Taiwan
关键词
D O I
10.2116/analsci.22.35
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An electrochemical cell coupled with disposable screen-printed electrodes (SPEs) that is specifically designed for use in flow injection analysis (FIA) is described in this study. The cell is made of foldable polyoxymethylene (acetal) thick platelets with the bottom portion consisting of a cavity track to drag the SPEs in position and the top portion having pre-drilled T-like holes to arrange the Ag/AgCl reference electrode and stainless steel inlet & outlet. An "O ring" is suitably fixed on the top of the working electrode to form a thin-layer space where the electrochemical reaction can take place. Hydrodynamic characterization was validated by using a benchmark hexacyanoferrate redox couple. The results of practical analysis of glucose in human plasma clearly demonstrate the characteristics and applicability of the proposed wall-jet electrochemical cell in FIA.
引用
收藏
页码:35 / 38
页数:4
相关论文
共 35 条
[1]   ELECTROCHEMISTRY AND DETECTION OF SOME ORGANIC AND BIOLOGICAL MOLECULES AT CONDUCTING POLY(3-METHYLTHIOPHENE) ELECTRODES [J].
ATTA, NF ;
GALAL, A ;
KARAGOZLER, AE ;
RUSSELL, GC ;
ZIMMER, H ;
MARK, HB .
BIOSENSORS & BIOELECTRONICS, 1991, 6 (04) :333-341
[2]   An electrochemical multienzymatic biosensor for determination of cholesterol [J].
Bongiovanni, C ;
Ferri, T ;
Poscia, A ;
Varalli, M ;
Santucci, R ;
Desideri, A .
BIOELECTROCHEMISTRY, 2001, 54 (01) :17-22
[3]  
Buchberger W, 1996, FRESEN J ANAL CHEM, V354, P797
[4]   Electrooxidation of ascorbic acid on the dispersed platinum glassy carbon electrode and its amperometric determination in blow injection analysis [J].
Casella, IG .
ELECTROANALYSIS, 1996, 8 (02) :128-134
[5]   Analysis of sugar phosphates and related compounds using capillary zone electrophoresis with indirect UV detection [J].
Ciringh, Y ;
Lindsey, JS .
JOURNAL OF CHROMATOGRAPHY A, 1998, 816 (02) :251-259
[6]   RAPID HETEROGENEOUS COMPETITIVE ELECTROCHEMICAL IMMUNOASSAY FOR IGG IN THE PICOMOLE RANGE [J].
DEALWIS, U ;
WILSON, GS .
ANALYTICAL CHEMISTRY, 1987, 59 (23) :2786-2789
[7]  
EGGERS HM, 1982, CLIN CHEM, V28, P1848
[8]   BIENZYME REACTOR FOR ELECTROCHEMICAL DETECTION OF LOW CONCENTRATIONS OF URIC-ACID AND GLUCOSE [J].
ELEKES, O ;
MOSCONE, D ;
VENEMA, K ;
KORF, J .
CLINICA CHIMICA ACTA, 1995, 239 (02) :153-165
[9]  
F Allen J Bard L.R., 2001, Electrochemical Methods: Fundamentals and Applications
[10]   THE CHARACTERIZATION OF IMMOBILIZED LIGNIN PEROXIDASE BY FLOW-INJECTION ANALYSIS [J].
FAWER, MS ;
STIERLI, J ;
CLIFFE, S ;
FIECHTER, A .
BIOCHIMICA ET BIOPHYSICA ACTA, 1991, 1076 (01) :15-22