[30]Heptaphyrin(1.1.1.1.1.0.0): an aromatic expanded porphyrin with a 'figure eight' like structure

被引:35
作者
Bucher, C [1 ]
Seidel, D [1 ]
Lynch, V [1 ]
Sessler, JL [1 ]
机构
[1] Univ Texas, Inst Mol & Cellular Biol, Dept Chem & Biochem, Austin, TX 78712 USA
关键词
D O I
10.1039/b109877b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, characterization, and X-ray structure of a heptapyrrolic macrocycle, [30]heptaphyrin(1.1.1.1.1.0.0) is reported; despite showing aromatic features, it exhibits a 'figure eight'-like structure in the solid state.
引用
收藏
页码:328 / 329
页数:2
相关论文
共 15 条
[1]   Meso aryl heptaphrins:: The first 30π aromatic expanded porphyrins with an inverted structure [J].
Anand, VRG ;
Pushpan, SK ;
Srinivasan, A ;
Narayanan, SJ ;
Sridevi, B ;
Chandrashekar, TK ;
Roy, R ;
Joshi, BS .
ORGANIC LETTERS, 2000, 2 (24) :3829-3832
[2]   Novel synthesis of hybrid calixphyrin macrocycles [J].
Bucher, C ;
Seidel, D ;
Lynch, V ;
Král, V ;
Sessler, JL .
ORGANIC LETTERS, 2000, 2 (20) :3103-3106
[3]   5,10,15,20-TETRAPHENYLSAPPHYRIN - IDENTIFICATION OF A PENTAPYRROLIC EXPANDED PORPHYRIN IN THE ROTHEMUND SYNTHESIS [J].
CHMIELEWSKI, PJ ;
LATOSGRAZYNSKI, L ;
RACHLEWICZ, K .
CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (01) :68-73
[5]   Synthesis and structural characterization of the first Schiff-base macrocycles containing terpyrrole subunits [J].
Meyer, S ;
Andrioletti, B ;
Sessler, JL ;
Lynch, V .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) :6752-6756
[6]   Synthesis of [28]heptaphyrin(1.0.0.1.0.0.0) and [32]octaphyrin(1.0.0.0.1.0.0.0) via a directed oxidative ring closure: The first expanded porphyrins containing a quaterpyrrole subunit [J].
Sessler, JL ;
Seidel, D ;
Lynch, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (48) :11257-11258
[7]   [26]Hexaphyrin(1.1.1.1.0.0): an all-aza isomer of rubyrin with an inverted pyrrole subunit [J].
Sessler, JL ;
Seidel, D ;
Bucher, C ;
Lynch, V .
CHEMICAL COMMUNICATIONS, 2000, (16) :1473-1474
[8]   Novel, terpyrrole-containing, aromatic expanded porphyrins [J].
Sessler, JL ;
Seidel, D ;
Bucher, C ;
Lynch, V .
TETRAHEDRON, 2001, 57 (17) :3743-3752
[9]   TURCASARIN, THE LARGEST EXPANDED PORPHYRIN TO DATE [J].
SESSLER, JL ;
WEGHORN, SJ ;
LYNCH, V ;
JOHNSON, MR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (14) :1509-1512
[10]   Synthesis and characterization of a stable smaragdyrin isomer [J].
Sessler, JL ;
Davis, JM ;
Lynch, V .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (20) :7062-7065