The chemical and structural origin of efficient p-type doping in P3HT

被引：274

作者：

Duong, Duc T. ^{[1
]}

Wang, Chenchen ^{[1
]}

Antono, Erin ^{[1
]}

Toney, Michael F. ^{[2
]}

Salleo, Alberto ^{[1
]}

机构：

[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA

[2] SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA

来源：

ORGANIC ELECTRONICS | 2013年 / 14卷 / 05期

基金：

美国国家科学基金会;

关键词：

Conjugated polymers; Doping; Organic electronics; Thin films; Organic semiconductors; CHARGE-TRANSFER ABSORPTION; ORGANIC ELECTRONICS; CONJUGATED POLYMERS; TRANSPORT; COMPLEX; VOLTAGE; DEVICES; LAYERS; FILMS;

D O I：

10.1016/j.orgel.2013.02.028

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We investigate the chemical and structural properties of solution-processed thin films of P3HT blended with p-type dopant F4TCNQ. The maximum in-plane electrical conductivity of doped films is observed at a molar doping fraction of 0.17, in agreement with the binding mechanism of F4TCNQ: P3HT complexes. Through the use of X-ray diffraction, a previously unreported crystalline phase is observed for P3HT films doped above a critical threshold concentration. This crystalline phase involves the incorporation of F4TCNQ molecules into ordered polymer regions and ultimately improves charge dissociation, leading to higher carrier density in thin film. Finally, optical absorption and X-ray diffraction reveal that the chemical state of P3HT in solution has a dramatic impact on the electrical and structural properties of the blended films. (C) 2013 Published by Elsevier B.V.

引用

页码：1330 / 1336

页数：7

共 34 条

[21] Charge-Transfer Localization in Molecularly Doped Thiophene-Based Donor Polymers [J].

Pingel, Patrick ;

Zhu, Lingyun ;

Park, Kue Surk ;

Vogel, Joern-Oliver ;

Janietz, Silvia ;

Kim, Eung-Gun ;

Rabe, Juergen P. ;

Bredas, Jean-Luc ;

Koch, Norbert .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (13) :2037-2041

[22] Use of a High Electron-Affinity Molybdenum Dithiolene Complex to p-Dope Hole-Transport Layers [J].

Qi, Yabing ;

Sajoto, Tissa ;

Barlow, Stephen ;

Kim, Eung-Gun ;

Bredas, Jean-Luc ;

Marder, Seth R. ;

Kahn, Antoine .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (35) :12530-+

[23] Rh-complex promoted synthesis of poly(arylacetylene) with pendant TTF units and formation of CT complexes of the polymer with π-acceptors [J].

Shimizu, T ;

Yamamoto, T .

INORGANICA CHIMICA ACTA, 1999, 296 (01) :278-280

[24]

Sze S.M., 2021, Physics of semiconductor devices

[25] Doping effects for organic photovoltaic cells based on small-molecular-weight semiconductors [J].

Taima, Tetsuya ;

Sakai, Jun ;

Yamanari, Toshihiro ;

Saito, Kazuhiro .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (6-7) :742-745

[26] Terahertz complex conductivities of carriers with partial localization in doped polythiophenes [J].

Unuma, Takeya ;

Fujii, Kenji ;

Kishida, Hideo ;

Nakamura, Arao .

APPLIED PHYSICS LETTERS, 2010, 97 (03)

[27] The relation between open-circuit voltage and the onset of photocurrent generation by charge-transfer absorption in polymer: Fullerene bulk heterojunction solar cells [J].

Vandewal, Koen ;

Gadisa, Abay ;

Oosterbaan, Wibren D. ;

Bertho, Sabine ;

Banishoeib, Fateme ;

Van Severen, Ineke ;

Lutsen, Laurence ;

Cleij, Thomas J. ;

Vanderzande, Dirk ;

Manca, Jean V. .

ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (14) :2064-2070

[28] Highly efficient organic devices based on electrically doped transport layers [J].

Walzer, K. ;

Maennig, B. ;

Pfeiffer, M. ;

Leo, K. .

CHEMICAL REVIEWS, 2007, 107 (04) :1233-1271

[29] 2-(2-Methoxyphenyl)-1,3-dimethyl-1H-benzoimidazol-3-ium Iodide as a New Air-Stable n-Type Dopant for Vacuum-Processed Organic Semiconductor Thin Films [J].

Wei, Peng ;

Menke, Torben ;

Naab, Benjamin D. ;

Leo, Karl ;

Riede, Moritz ;

Bao, Zhenan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) :3999-4002

[30] n-type doping of organic thin films using cationic dyes [J].

Werner, A ;

Li, FH ;

Harada, K ;

Pfeiffer, M ;

Fritz, L ;

Leo, K ;

Machill, S .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (03) :255-260

← 1 2 3 4 →