Tetravalent Silicon Connectors MenSi(p-C6H4CO2H)4-n (n=0, 1, 2) for the Construction of Metal-Organic Frameworks

被引：60

作者：

Davies, R. P. ^{[1
]}

Less, R. J. ^{[1
]}

Lickiss, P. D. ^{[1
]}

Robertson, K. ^{[1
]}

White, A. J. P. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 21期

基金：

英国自然环境研究理事会; 英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ic801174d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of silicon-centered connecting units, MenSi(p-C6H4CO2H)(4-n) (n = 0, 1, 2), have been prepared and their coordination polymers with Zn(II) metal atoms studied. The tetra-acid L1 (n = 0) acts as a tetrahedral node and reacts with Zn(II) centers to give 1, a novel interpenetrating 3D network containing distorted tetrahedral bimetallic secondary building units (SBUs). The triacid L2 (n = 1) acts as a trigonal pyramidal node and forms an intercalated 2D layered network, 2, with Zn(II) ions, containing distorted octahedral tetranuclear SBUs. Last, the bent diacid L3 (n = 2) reacts with Zn(II) centers to give 3, a corrugated 2D layered structure containing 1D zinc hydroxo chains. Together these three new coordination polymers demonstrate the potential versatility of tetravalent silicon containing connecting ligands for metal-organic framework construction.

引用

页码：9958 / 9964

页数：7

共 54 条

[1]

[Anonymous], 1998, SHELX 97

[2] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[3] 1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal-organic frameworks [J].

Braun, ME ;

Steffek, CD ;

Kim, J ;

Rasmussen, PG ;

Yaghi, OM .

CHEMICAL COMMUNICATIONS, 2001, (24) :2532-2533

[4]

Carlucci L, 1999, CHEM-EUR J, V5, P237, DOI 10.1002/(SICI)1521-3765(19990104)5:1<237::AID-CHEM237>3.0.CO

[5]

2-T

[6] Six-coordinated Cd(II) centers as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine [J].

Cordes, David B. ;

Hanton, Lyall R. ;

Spicer, Mark D. .

CRYSTAL GROWTH & DESIGN, 2007, 7 (02) :328-336

[7] The use of H-bonding to increase the dimensionality of coordination networks of Cu(I) and Cu(II) [J].

Cordes, David B. ;

Hanton, Lyall R. ;

Spicer, Mark D. .

JOURNAL OF MOLECULAR STRUCTURE, 2006, 796 (1-3) :146-159

[8] Solid-state structures of zinc(II) benzoate complexes. Catalyst precursors for the coupling of carbon dioxide and epoxides [J].

Darensbourg, DJ ;

Wildeson, JR ;

Yarbrough, JC .

INORGANIC CHEMISTRY, 2002, 41 (04) :973-980

[9] High oxidation state aqueous organometallics.: Formation and structure of an oxo-centred Cp* MoV trinuclear cation by chemical reduction of Cp*2Mo2O5 [J].

Demirhan, F ;

Gun, J ;

Lev, O ;

Modestov, A ;

Poli, R ;

Richard, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (10) :2109-2111

[10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

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