Band offsets of atomic-layer-deposited Al2O3 on GaAs and the effects of surface treatment

被引:67
作者
Nguyen, N. V. [1 ]
Kirillov, Oleg A. [1 ]
Jiang, W. [1 ]
Wang, Wenyong [1 ]
Suehle, John S. [1 ]
Ye, P. D. [2 ,3 ]
Xuan, Y. [4 ]
Goel, N. [4 ]
Choi, K. -W. [4 ]
Tsai, Wilman [4 ]
Sayan, S. [4 ]
机构
[1] Natl Inst Stand & Technol, Div Semicond Elect, Gaithersburg, MD 20899 USA
[2] Purdue Univ, Sch Elect & Comp Engn, W Lafayette, IN 47907 USA
[3] Purdue Univ, Birck Nanotechnol Ctr, W Lafayette, IN 47907 USA
[4] Intel Corp, Santa Clara, CA 95052 USA
关键词
D O I
10.1063/1.2976676
中图分类号
O59 [应用物理学];
学科分类号
摘要
The metal gate/high-k dielectric/III-V semiconductor band alignment is one of the most technologically important parameters. We report the band offsets of the Al/Al(2)O(3)/GaAs structure and the effect of GaAs surface treatment. The energy barrier at the Al(2)O(3) and sulfur-passivated GaAs interface is found to be 3.0 +/- 0.1 eV whereas for the unpassivated or NH(4)OH-treated GaAs is 3.6 eV. At the Al/Al(2)O(3) interface, all samples yield the same barrier height of 2.9 +/- 0.2 eV. With a band gap of 6.4 +/- 0.05 eV for Al(2)O(3), the band alignments at both Al(2)O(3) interfaces are established. (C) 2008 American Institute of Physics.
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页数:3
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