Ruthenium Complexes with Cooperative CNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane

被引：271

作者：

Kaess, Martina ^{[1
]}

Friedrich, Anja ^{[1
]}

Drees, Markus ^{[1
]}

Schneider, Sven ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 05期

关键词：

cooperative effects; dehydrogenation; pi interactions; PNP ligands; ruthenium; BORON-NITROGEN BONDS; HYDROGENATION; MECHANISM; AMINOBORANES; GENERATION; BORAZINES; ALCOHOLS; ADDUCTS; KETONES; ROUTE;

D O I：

10.1002/anie.200805108

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) GRu"vy reactivity: The new ruthenium(II) complex having cooperative PNP enamido ligand A reversibly activates two equivalents H2 under reversible hydrogenation of amido (B) and amino (C) complexes. B exhibits the highest reported activities in the dehydrocoupling of ammonia-borane. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：905 / 907

页数：3

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