CO2 as a C1-building block for the catalytic methylation of amines

被引：300

作者：

Jacquet, Olivier ^{[1
]}

Frogneux, Xavier ^{[1
]}

Gomes, Christophe Das Neves ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA, IRAMIS, SIS2M, CNRS UMR 3299, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL SCIENCE | 2013年 / 4卷 / 05期

关键词：

CARBON-DIOXIDE; CARBOXYLIC-ACIDS; FORMIC-ACID; REDUCTION; HYDROSILYLATION; METHANOL; IRON; FUNCTIONALIZATION; TRANSFORMATION; HYDROGENATION;

D O I：

10.1039/c3sc22240c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel catalytic reaction has been designed to utilize, for the first time, CO2 as a C-1 feedstock in the synthesis of N-methylamines. Simple zinc catalysts, based on commercially available zinc salts and ligands, prove highly efficient in promoting both a 6 electron reduction of carbon dioxide and the formation of a C-N bond, using hydrosilanes and amines.

引用

页码：2127 / 2131

页数：5

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