Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium-Phosphine Catalyst

被引：440

作者：

Wesselbaum, Sebastian ^{[1
]}

vom Stein, Thorsten ^{[1
]}

Klankermayer, Juergen ^{[1
]}

Leitner, Walter ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 30期

关键词：

carbon dioxide; homogeneous catalysis; hydrogenation; methanol; ruthenium; FORMIC-ACID; METAL-COMPLEXES; CO2; DERIVATIVES; RHODIUM; LIGAND; TRANSFORMATION; ACTIVATION; OSMIUM;

D O I：

10.1002/anie.201202320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simply efficient: The homogenously catalyzed hydrogenation of CO 2 to methanol is achieved by using a ruthenium phosphine complex under relatively mild conditions (see scheme; HNTf 2= bis(trifluoromethane)sulfonimide). This is the first example of CO 2 hydrogenation to methanol by using a single molecularly defined catalyst. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7499 / 7502

页数：4

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