Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C-N, C-O, and C-C Bonds

被引：146

作者：

Jin, Guanghua

Werncke, C. Gunnar

Escudie, Yannick

Sabo-Etienne, Sylviane ^{[1
]}

Bontemps, Sebastien

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 30期

关键词：

TRANSITION-METAL-COMPLEXES; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; MOLECULAR-HYDROGEN; AMINES; METHYLATION; METHANOL; CONVERSION; TRANSFORMATION; TECHNOLOGIES;

D O I：

10.1021/jacs.5b06077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein the use of the (dihydrido) iron catalyst, Fe(H)(2)(dmpe)(2), for the selective reduction of CO2 into either bis(boryl)acetal or methoxyborane depending on the hydroborane used as a reductant. In a one-pot two-step procedure, the in situ generated bis(boryl)acetal was Shown to be a reactive and versatile source of methylene to create new C-N but also C-O and C-C bonds.

引用

收藏

页码：9563 / 9566

页数：4

相关论文

共 59 条

[1] Reductive disproportionation of carbon dioxide at an iron(II) center [J].

Allen, Olivia R. ;

Dalgarno, Scott J. ;

Field, Leslie D. .

ORGANOMETALLICS, 2008, 27 (14) :3328-3330

[2] Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation [J].

Appel, Aaron M. ;

Bercaw, John E. ;

Bocarsly, Andrew B. ;

Dobbek, Holger ;

DuBois, Daniel L. ;

Dupuis, Michel ;

Ferry, James G. ;

Fujita, Etsuko ;

Hille, Russ ;

Kenis, Paul J. A. ;

Kerfeld, Cheal A. ;

Morris, Robert H. ;

Peden, Charles H. F. ;

Portis, Archie R. ;

Ragsdale, Stephen W. ;

Rauchfuss, Thomas B. ;

Reek, Joost N. H. ;

Seefeldt, Lance C. ;

Thauer, Rudolf K. ;

Waldrop, Grover L. .

CHEMICAL REVIEWS, 2013, 113 (08) :6621-6658

[3]

Aresta M., 2006, ACTIVATION SMALL MOL, P1, DOI [DOI 10.1002/9783527609352.CHL, 10.1002/9783527609352.ch1, DOI 10.1002/9783527609352.CH1]

[4] Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2 [J].

Aresta, Michele ;

Dibenedetto, Angela ;

Angelini, Antonella .

CHEMICAL REVIEWS, 2014, 114 (03) :1709-1742

[5] Synthetic Routes to N-Heterocyclic Carbene Precursors [J].

Benhamou, Laure ;

Chardon, Edith ;

Lavigne, Guy ;

Bellemin-Laponnaz, Stephane ;

Cesar, Vincent .

CHEMICAL REVIEWS, 2011, 111 (04) :2705-2733

[6] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels [J].

Benson, Eric E. ;

Kubiak, Clifford P. ;

Sathrum, Aaron J. ;

Smieja, Jonathan M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :89-99

[7] Ruthenium-Catalyzed Reductive Methylation of Imines Using Carbon Dioxide and Molecular Hydrogen [J].

Beydoun, Kassem ;

Ghattas, Ghazi ;

Thenert, Katharina ;

Klankermayer, Juergen ;

Leitner, Walter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (41) :11010-11014

[8] Ruthenium-Catalyzed Direct Methylation of Primary and Secondary Aromatic Amines Using Carbon Dioxide and Molecular Hydrogen [J].

Beydoun, Kassem ;

vom Stein, Thorsten ;

Klankermayer, Juergen ;

Leitner, Walter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (36) :9554-9557

[9]

BLAZEVIC N, 1979, SYNTHESIS-STUTTGART, P161

[10] Boron-mediated activation of carbon dioxide [J].

Bontemps, Sebastien .

COORDINATION CHEMISTRY REVIEWS, 2016, 308 :117-130

← 1 2 3 4 5 6 →