Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C-N, C-O, and C-C Bonds

被引：146

作者：

Jin, Guanghua

Werncke, C. Gunnar

Escudie, Yannick

Sabo-Etienne, Sylviane ^{[1
]}

Bontemps, Sebastien

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 30期

关键词：

TRANSITION-METAL-COMPLEXES; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; MOLECULAR-HYDROGEN; AMINES; METHYLATION; METHANOL; CONVERSION; TRANSFORMATION; TECHNOLOGIES;

D O I：

10.1021/jacs.5b06077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein the use of the (dihydrido) iron catalyst, Fe(H)(2)(dmpe)(2), for the selective reduction of CO2 into either bis(boryl)acetal or methoxyborane depending on the hydroborane used as a reductant. In a one-pot two-step procedure, the in situ generated bis(boryl)acetal was Shown to be a reactive and versatile source of methylene to create new C-N but also C-O and C-C bonds.

引用

收藏

页码：9563 / 9566

页数：4

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