Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N-H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

被引：322

作者：

Jacquet, Olivier ^{[1
]}

Gomes, Christophe Das Neves ^{[1
]}

Ephritikhine, Michel ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA Saclay, CEA, IRAMIS, SIS2M,CNRS,UMR 3299, F-91191 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 06期

关键词：

REDUCTION; TRANSFORMATION; HYDROGENATION; CATALYSIS; COMPLEXES;

D O I：

10.1021/ja211527q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly active organocatalytic system based on N-heterocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen molecules and heterocycles, using two chemical wastes: CO2 and polymethylhydrosiloxane (PMHS).

引用

页码：2934 / 2937

页数：4

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