Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N-H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

被引：322

作者：

Jacquet, Olivier ^{[1
]}

Gomes, Christophe Das Neves ^{[1
]}

Ephritikhine, Michel ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA Saclay, CEA, IRAMIS, SIS2M,CNRS,UMR 3299, F-91191 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 06期

关键词：

REDUCTION; TRANSFORMATION; HYDROGENATION; CATALYSIS; COMPLEXES;

D O I：

10.1021/ja211527q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly active organocatalytic system based on N-heterocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen molecules and heterocycles, using two chemical wastes: CO2 and polymethylhydrosiloxane (PMHS).

引用

页码：2934 / 2937

页数：4

共 24 条

[11] Transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide [J].

Huang, Kun ;

Sun, Chang-Liang ;

Shi, Zhang-Jie .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) :2435-2452

[12] CATALYTIC PRODUCTION OF DIMETHYLFORMAMIDE FROM SUPERCRITICAL CARBON-DIOXIDE [J].

JESSOP, PG ;

HSIAO, Y ;

IKARIYA, T ;

NOYORI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) :8851-8852

[13] Amphiphilic resin-supported ruthenium(II) complexes as recyclable catalysts for the hydrogenation of supercritical carbon dioxide [J].

Kayaki, Y ;

Shimokawatoko, Y ;

Ikariya, T .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :175-179

[14] Polymethylhydrosiloxane: a versatile reducing agent for organic synthesis [J].

Lawrence, NJ ;

Drew, MD ;

Bushell, SM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (23) :3381-3391

[15] Nonracemic diarylmethanols from CuH-Catalyzed hydrosilylation of diaryl ketones [J].

Lee, Ching-Tien ;

Lipshutz, Bruce H. .

ORGANIC LETTERS, 2008, 10 (19) :4187-4190

[16] Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide [J].

Liu, FC ;

Abrams, MB ;

Baker, RT ;

Tumas, W .

CHEMICAL COMMUNICATIONS, 2001, (05) :433-434

[17] Anthropogenic Chemical Carbon Cycle for a Sustainable Future [J].

Olah, George A. ;

Prakash, G. K. Surya ;

Goeppert, Alain .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (33) :12881-12898

[18] Pd-catalyzed silicon hydride reductions of aromatic and aliphatic nitro groups [J].

Rahaim, RJ ;

Maleczka, RE .

ORGANIC LETTERS, 2005, 7 (22) :5087-5090

[19] C-O Hydrogenolysis Catalyzed by Pd-PMHS Nanoparticles in the Company of Chloroarenes [J].

Rahaim, Ronald J., Jr. ;

Maleczka, Robert E., Jr. .

ORGANIC LETTERS, 2011, 13 (04) :584-587

[20] Recent developments in carbon dioxide utilization under mild conditions [J].

Riduan, Siti Nurhanna ;

Zhang, Yugen .

DALTON TRANSACTIONS, 2010, 39 (14) :3347-3357

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