Nanoscale Porous Framework of Lithium Titanate for Ultrafast Lithium Insertion

被引：169

作者：

Feckl, Johann M. ^{[1
,2
]}

Fominykh, Ksenia ^{[1
,2
]}

Doeblinger, Markus ^{[1
,2
]}

Fattakhova-Rohlfing, Dina ^{[1
,2
]}

Bein, Thomas ^{[1
,2
]}

机构：

[1] Univ Munich LMU, Dept Chem, D-81377 Munich, Germany

[2] Univ Munich LMU, Ctr Nanosci CeNS, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 30期

关键词：

lithium insertion; lithium titanate; nanocrystals; solvothermal synthesis; ultrafast materials; NANOCRYSTALLINE LI4TI5O12; RATE PERFORMANCE; ENERGY-STORAGE; NANOPARTICLES; BATTERIES; CHARGE;

D O I：

10.1002/anie.201201463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous lithium titanate has been prepared with a titanate morphology that leads to the fastest insertion of lithium. It features a gravimetric capacity of about 175 mAhg -1 and delivers up to 73% of the maximum capacity at up to 800 C (4.5 s) without deterioration over 1000 cycles. A key feature is a fully crystalline interconnected porous framework composed of spinel nanocrystals of only a few nanometers in size. Scale bar: 10 nm. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7459 / 7463

页数：5

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