A new treatment for kinetics of oxidation of silicon carbide

被引:29
作者
Hou, Xin-mei [1 ]
Chou, Kuo-Chih [1 ,3 ]
Li, Fu-shen [2 ]
机构
[1] Univ Sci & Technol Beijing, Met & Ecol Engn Sch, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[3] Shanghai Univ, Dept Mat Sci & Engn, Shanghai 200072, Peoples R China
关键词
Oxidation; Mechanism; Kinetics; SiC; SI3N4; VAPOR; NITRIDE; OXYGEN;
D O I
10.1016/j.ceramint.2008.01.015
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper the oxidation kinetics of SiC has been studied as per both experimental and theoretical aspects based on current literatures, from which the shortcoming of theory has been discussed. A new model has been introduced that can express the oxidation weight gain as a function of temperature, oxygen partial pressure and the size of materials explicitly. Two examples, chemical vapor deposition (CVD) SiC pellet and ZrB2-SiC pellet, have been selected to test our new model and the calculated results show that our new model can tit both isothermal and non-isothermal data very well. Therefore, it is expected that this new model could be used to predict the oxidation behavior of SiC materials based on limited experimental information. (C) 2008 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:603 / 607
页数:5
相关论文
共 17 条
[1]   A kinetic model for oxidation of Si-Al-O-N materials [J].
Chou, KC .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (05) :1568-1576
[2]  
Cotello JA, 1986, J AM CERAM SOC, V69, P674
[3]   THERMODYNAMICS OF THE SI-N-O SYSTEM AND KINETIC MODELING OF OXIDATION OF SI3N4 [J].
DU, HH ;
TRESSLER, RE ;
SPEAR, KE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (11) :3210-3215
[4]  
DU WF, 1992, J CHIN CERAM SOC, V20, P417
[5]   OXIDATION OF SILICON CARBIDE AT 1150 DEGREES TO 1400 DEGREES C AND AT 9 X 10 TO 5 X 10-1 TORR OXYGEN PRESSURE [J].
GULBRANS.EA ;
ANDREW, KF ;
BRASSART, FA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1966, 113 (12) :1311-&
[6]   A new measurement and treatment for kinetics of isothermal oxidation of Si3N4 [J].
Hou, Xin-mei ;
Chou, Kuo-chih ;
Hu, Xiao-jun ;
Zhao, Hai-lei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 459 (1-2) :123-129
[7]   Thermal stability of high surface area silicon carbide materials [J].
Krawiec, Piotr ;
Kaskel, Stefan .
JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (08) :2281-2289
[8]   Evaluation of ultra-high temperature ceramics for aeropropulsion use [J].
Levine, SR ;
Opila, EJ ;
Halbig, MC ;
Kiser, JD ;
Singh, M ;
Salem, JA .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (14-15) :2757-2767
[9]   SOME NEW PERSPECTIVES ON OXIDATION OF SILICON-CARBIDE AND SILICON-NITRIDE [J].
LUTHRA, KL .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (05) :1095-1103
[10]   A COMPARISON OF THE OXIDATION-KINETICS OF SIC AND SI3N4 [J].
OGBUJI, LUJT ;
OPILA, EJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (03) :925-930