A study on the novel d-f heterodinuclear Gd(III)-Ni(II) cryptate: Synthesis, crystal structure, and magnetic behavior

被引:61
作者
Chen, QY
Luo, QH [1 ]
Zheng, LM
Wang, ZL
Chen, JT
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Beijing Univ, State Key Lanthanide Mat Chem, Beijing 100008, Peoples R China
[3] FuZhou State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词
D O I
10.1021/ic010270y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel d-f heterodinuclear Gd(III)-Ni(II) cryptate was synthesized by a stepwise method using the mononuclear Gd(III) cryptate as precursor. A quantitative analysis shows that the Gd(M)-Ni(II) interaction is of the ferromagnetic type.
引用
收藏
页码:605 / +
页数:6
相关论文
共 34 条
[1]   Metal template synthesis of lanthanide cryptates. Crystal structure of a dysprosium cryptate [J].
Avecilla, F ;
Bastida, R ;
deBlas, A ;
Fenton, DE ;
Macias, A ;
Rodriguez, A ;
RodriguezBlas, T ;
GarciaGranda, S ;
CorzoSuarez, R .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (03) :409-413
[2]   CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS [J].
BENCINI, A ;
BENELLI, C ;
CANESCHI, A ;
CARLIN, RL ;
DEI, A ;
GATTESCHI, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8128-8136
[3]   RARE-EARTH SPECTROSCOPY IN RELATION TO MATERIALS SCIENCE [J].
BLASSE, G .
MATERIALS CHEMISTRY AND PHYSICS, 1992, 31 (1-2) :3-6
[4]   Cooperative bimetallic redox reactivity [J].
Bosnich, B .
INORGANIC CHEMISTRY, 1999, 38 (11) :2554-2562
[5]   Heterometallic complexes containing d- and f-block elements: Synthesis and structural characterisation of novel Ni-Er and Co-Dy compounds [J].
Brechin, EK ;
Harris, SG ;
Parsons, S ;
Winpenny, REP .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (10) :1665-1666
[6]   Synthesis and crystal structure of the first d-f heterodinuclear Dy(III)-Cu(II) cryptate [J].
Chen, QY ;
Luo, QH ;
Wang, ZL ;
Chen, JT .
CHEMICAL COMMUNICATIONS, 2000, (12) :1033-1034
[7]   Synthesis and crystal structure of an unsymmetric gadolinium(III) cryptate [J].
Chen, QY ;
Luo, QH ;
Liu, YJ ;
Duan, CY .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (03) :177-180
[8]  
CONNOR CJ, 1982, PROGR INORGANIC CHEM, V29, P203
[9]   Is ferromagnetism an intrinsic property of the CuII/GdIII couple?: 1.: Structures and magnetic properties of two novel dinuclear complexes with a μ-phenolato-μ-oximato (Cu,Gd) core [J].
Costes, JP ;
Dahan, F ;
Dupuis, A ;
Laurent, JP .
INORGANIC CHEMISTRY, 2000, 39 (02) :169-173
[10]   A general route to strictly dinuclear Cu(II)/Ln(III) complexes. Structural determination and magnetic behavior of two Cu(II)/Gd(III) complexes [J].
Costes, JP ;
Dahan, F ;
Dupuis, A ;
Laurent, JP .
INORGANIC CHEMISTRY, 1997, 36 (16) :3429-3433