Optical and structural studies in InGaN quantum well structure laser diodes

An InGaN multiple-quantum-well laser diode wafer that lased at around 400 nm was shown to have the InN mole fraction, x, of only 6% in the wells. Nanometer-probe compositional analysis showed that the fluctuation of x was as small as 1% or less, which is the resolution limit. However, the wells exhibited a Stokes-like shift (SS) of 49 meV at 300 K, which was approximately 65% of the luminescence linewidth, and effective localization depth, E-0, was estimated to be 35 meV at 300 K. Since the effective electric field due to polarization in the wells was estimated to be as small as 300 kV/cm, SS was considered to originate from effective band-gap inhomogeneity. Because the well thickness fluctuation was insufficient to reproduce SS or E-0 and bulk cubic In0.02Ga0.98N that does not suffer any polarization field or thickness fluctuation effect exhibited a SS of 140 meV at 77 K, the exciton localization is considered to be an intrinsic phenomenon in InGaN, which is due to the large band-gap bowing and In clustering in InGaN material. The spontaneous emission from the InGaN wells was thus assigned as being due to the recombination of excitons localized at the exponential tail-type potential minima in the density of states. The upper bound of the lateral localization size has been estimated to be 50 nm. Such shallow and low density localized states are leveled by injecting high density carriers under the lasing conditions. (C) 2001 American Vacuum Society.