Grain boundaries as preferential sites for resistive switching in the HfO2 resistive random access memory structures

被引:177
作者
Lanza, M. [1 ]
Zhang, K. [2 ]
Porti, M. [1 ]
Nafria, M. [1 ]
Shen, Z. Y. [2 ]
Liu, L. F. [3 ]
Kang, J. F. [3 ]
Gilmer, D. [4 ]
Bersuker, G. [4 ]
机构
[1] Univ Autonoma Barcelona, Dept Elect Engn, Bellaterra 08193, Spain
[2] Peking Univ, Dept Elect, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China
[3] Peking Univ, Inst Microelect, Beijing 100871, Peoples R China
[4] SEMATECH, Austin, TX 78741 USA
基金
中国国家自然科学基金;
关键词
BREAKDOWN;
D O I
10.1063/1.3697648
中图分类号
O59 [应用物理学];
学科分类号
摘要
Resistive switching (RS) phenomenon in the HfO2 dielectric has been indirectly observed at device level in previous studies using metal-insulator-metal structures, but its origin remains unclear. In this work, using the enhanced conductive atomic force microscope (ECAFM), we have been able to obtain in situ direct observation of RS with nanometric resolution. The ECAFM measurements reveal that the conductive filaments exhibiting the RS are primarily formed at the grain boundaries, which were shown exhibiting especially low breakdown voltage due to their intrinsic high density of the oxygen vacancies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3697648]
引用
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页数:4
相关论文
共 18 条
[1]   Highly scalable non-volatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses [J].
Baek, IG ;
Lee, MS ;
Seo, S ;
Lee, MJ ;
Seo, DH ;
Suh, DS ;
Park, JC ;
Park, SO ;
Kim, HS ;
Yoo, IK ;
Chung, UI ;
Moon, JT .
IEEE INTERNATIONAL ELECTRON DEVICES MEETING 2004, TECHNICAL DIGEST, 2004, :587-590
[2]   Grain boundary-driven leakage path formation in HfO2 dielectrics [J].
Bersuker, G. ;
Yum, J. ;
Vandelli, L. ;
Padovani, A. ;
Larcher, L. ;
Iglesias, V. ;
Porti, M. ;
Nafria, M. ;
McKenna, K. ;
Shluger, A. ;
Kirsch, P. ;
Jammy, R. .
SOLID-STATE ELECTRONICS, 2011, 65-66 :146-150
[3]  
Bersuker G, 2010, INT EL DEVICES MEET
[4]  
Bersuker G., 2011, P 2011 3 IEEE INT ME, P1, DOI [10.1109/IMW.2011.5873225, DOI 10.1109/IMW.2011.5873225]
[5]   Enhanced electrical performance for conductive atomic force microscopy [J].
Blasco, X ;
Nafria, M ;
Aymerich, X .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2005, 76 (01)
[6]   Study on the resistive switching time of TiO2 thin films [J].
Choi, Byung Joon ;
Choi, Seol ;
Kim, Kyung Min ;
Shin, Yong Cheol ;
Hwang, Cheol Seong ;
Hwang, Sung-Yeon ;
Cho, Sung-sil ;
Park, Sanghyun ;
Hong, Suk-Kyoung .
APPLIED PHYSICS LETTERS, 2006, 89 (01)
[7]   Reversible dielectric breakdown in ultrathin Hf based high-k stacks under current-limited stresses [J].
Crespo-Yepes, A. ;
Martin-Martinez, J. ;
Rodriguez, R. ;
Nafria, M. ;
Aymerich, X. .
MICROELECTRONICS RELIABILITY, 2009, 49 (9-11) :1024-1028
[8]   IMPACT IONIZATION, TRAP CREATION, DEGRADATION, AND BREAKDOWN IN SILICON DIOXIDE FILMS ON SILICON [J].
DIMARIA, DJ ;
CARTIER, E ;
ARNOLD, D .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (07) :3367-3384
[9]   Ultrathin HfO2 films grown on silicon by atomic layer deposition for advanced gate dielectrics applications [J].
Gusev, EP ;
Cabral, C ;
Copel, M ;
D'Emic, C ;
Gribelyuk, M .
MICROELECTRONIC ENGINEERING, 2003, 69 (2-4) :145-151
[10]   Correlation between the nanoscale electrical and morphological properties of crystallized hafnium oxide-based metal oxide semiconductor structures [J].
Iglesias, V. ;
Porti, M. ;
Nafria, M. ;
Aymerich, X. ;
Dudek, P. ;
Schroeder, T. ;
Bersuker, G. .
APPLIED PHYSICS LETTERS, 2010, 97 (26)