Towards the development of a hydrogen battery

被引：144

作者：

Boddien, Albert ^{[1
]}

Federsel, Christopher ^{[1
]}

Sponholz, Peter ^{[1
]}

Mellmann, Doerthe ^{[1
]}

Jackstell, Ralf ^{[1
]}

Junge, Henrik ^{[1
]}

Laurenczy, Gabor ^{[2
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2012年 / 5卷 / 10期

基金：

瑞士国家科学基金会;

关键词：

FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; STORAGE MATERIAL; GENERATION; CO2; COMPLEXES; TEMPERATURE; CATALYSTS; ADDUCTS;

D O I：

10.1039/c2ee22043a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel Ru-catalyzed hydrogenation of carbon dioxide proceeds with an unprecedented high formic acid to amine ratio (AAR of 2.69), which results in an improved energy content. The presented catalyst system allows for reversible fast hydrogen loading (even at RT) and unprecedented unloading (TON for H-2 liberation of 800 000).

引用

页码：8907 / 8911

页数：5

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