Mononuclear tris(2-mercapto-1-arylimidazolyl)hydroborato complexes of zinc, [TmAr]ZnX:: structural evidence that a sulfur rich coordination environment promotes the formation of a tetrahedral alcohol complex in a synthetic analogue of LADH

被引：104

作者：

Kimblin, C ^{[1
]}

Bridgewater, BM ^{[1
]}

Churchill, DG ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a906561j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tris(2-mercapto-1-mesitylimidazolyl)borate ligand, [Tm-Mes](-), has been used to synthesize {[Tm-Mes]Zn(HOMe)}(+), a stable monomeric tetrahedral zinc-methanol complex which resembles the proposed alcohol intermediate in the catalytic cycle of the mechanism of action of liver alcohol dehydrogenase.

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页码：2301 / 2302

页数：2

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