A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules

被引：220

作者：

Chen, Banglin ^{[1
]}

Ma, Shengqian

Hurtado, Eric J.

Lobkovsky, Emil B.

Zhou, Hong-Cai

机构：

[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA

[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

[3] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 21期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ic7014034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5)center dot xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 angstrom, the activated 1a exhibits highly selective sorption behavior toward H-2/N-2, H-2/CO, and CO2/CH4.

引用

页码：8490 / 8492

页数：3

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