A new thiophene substituted isoindigo based copolymer for high performance ambipolar transistors

被引：242

作者：

Ashraf, Raja Shahid ^{[1
]}

Kronemeijer, Auke Jisk ^{[2
]}

James, David Ian ^{[1
]}

Sirringhaus, Henning ^{[2
]}

McCulloch, Iain ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Ctr Plast Elect, London SW7 2AZ, England

[2] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 33期

基金：

英国工程与自然科学研究理事会;

关键词：

FIELD-EFFECT TRANSISTORS; SEMICONDUCTING POLYMERS; CONJUGATED POLYMERS; SIDE-CHAINS; MOBILITIES; ACCEPTOR; PACKING; DONOR; HOLE;

D O I：

10.1039/c2cc30169e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel thiophene substituted isoindigo and its copolymer with benzothiadiazole have been synthesized. The polymer with low lying LUMO energy levels exhibits excellent ambipolar behavior in field effect transistors with both hole and electron mobilities recorded over 0.1 cm(2) V-1 s(-1).

引用

页码：3939 / 3941

页数：3

共 20 条

[1] Silaindacenodithiophene Semiconducting Polymers for Efficient Solar Cells and High-Mobility Ambipolar Transistors [J].

Ashraf, Raja Shahid ;

Chen, Zhuoying ;

Leem, Dong Seok ;

Bronstein, Hugo ;

Zhang, Weimin ;

Schroeder, Bob ;

Geerts, Yves ;

Smith, Jeremy ;

Watkins, Scott ;

Anthopoulos, Thomas D. ;

Sirringhaus, Henning ;

de Mello, John C. ;

Heeney, Martin ;

McCulloch, Iain .

CHEMISTRY OF MATERIALS, 2011, 23 (03) :768-770

[2] Facile Synthesis of 1,1′-Dialkylisoindigos through Deoxygenation Reaction of Isatins and Tris(diethylamino)phosphine [J].

Bogdanov, Andrei V. ;

Mironov, Vladimir F. ;

Musin, Lenar I. ;

Musin, Rashid Z. .

SYNTHESIS-STUTTGART, 2010, (19) :3268-3270

[3] Thieno[3,2-b]thiophene-Diketopyrrolopyrrole-Containing Polymers for High-Performance Organic Field-Effect Transistors and Organic Photovoltaic Devices [J].

Bronstein, Hugo ;

Chen, Zhuoying ;

Ashraf, Rap Shahid ;

Zhang, Weimin ;

Du, Junping ;

Durrant, James R. ;

Tuladhar, Pabitra Shakya ;

Song, Kigook ;

Watkins, Scott E. ;

Geerts, Yves ;

Wienk, Martijn M. ;

Janssen, Rene A. J. ;

Anthopoulos, Thomas ;

Sirringhaus, Henning ;

Heeney, Martin ;

McCulloch, Iain .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (10) :3272-3275

[4] High-Performance Ambipolar Diketopyrrolopyrrole-Thieno[3,2-b]thiophene Copolymer Field-Effect Transistors with Balanced Hole and Electron Mobilities [J].

Chen, Zhuoying ;

Lee, Mi Jung ;

Ashraf, Raja Shahid ;

Gu, Yun ;

Albert-Seifried, Sebastian ;

Nielsen, Martin Meedom ;

Schroeder, Bob ;

Anthopoulos, Thomas D. ;

Heeney, Martin ;

McCulloch, Iain ;

Sirringhaus, Henning .

ADVANCED MATERIALS, 2012, 24 (05) :647-+

[5] Poly(diketopyrrolopyrrole-benzothiadiazole) with Ambipolarity Approaching 100% Equivalency [J].

Cho, Shinuk ;

Lee, Junghoon ;

Tong, Minghong ;

Seo, Jung Hwa ;

Yang, Changduk .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (10) :1910-1916

[6] General observation of n-type field-effect behaviour in organic semiconductors [J].

Chua, LL ;

Zaumseil, J ;

Chang, JF ;

Ou, ECW ;

Ho, PKH ;

Sirringhaus, H ;

Friend, RH .

NATURE, 2005, 434 (7030) :194-199

[7] Effects of packing structure on the optoelectronic and charge transport properties in poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) [J].

Donley, CL ;

Zaumseil, J ;

Andreasen, JW ;

Nielsen, MM ;

Sirringhaus, H ;

Friend, RH ;

Kim, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (37) :12890-12899

[8] Reactions of cyclic oxalyl compounds .38. New Isoindigoide dyes from heterocyclic 2,3-diones - Synthesis and thermal rearrangement [J].

Kollenz, G ;

Penn, G ;

Theuer, R ;

Fabian, WMF ;

ElNabi, HAA ;

Zhang, X ;

Peters, K ;

Peters, EM ;

vonSchnering, HG .

TETRAHEDRON, 1996, 52 (15) :5427-5440

[9] High-Performance Air-Stable Organic Field-Effect Transistors: Isoindigo-Based Conjugated Polymers [J].

Lei, Ting ;

Cao, Yue ;

Fan, Yunlong ;

Liu, Chen-Jiang ;

Yuan, Si-Chun ;

Pei, Jian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (16) :6099-6101

[10] Low bandgap isoindigo-based copolymers: design, synthesis and photovoltaic applications [J].

Liu, Bo ;

Zou, Yingping ;

Peng, Bo ;

Zhao, Bin ;

Huang, Kelong ;

He, Yuehui ;

Pan, Chunyue .

POLYMER CHEMISTRY, 2011, 2 (05) :1156-1162

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