Synthesis of novel N,O-planar chiral [2,2]paracyclophane ligands and their application as catalysts in the addition of diethylzinc to aldehydes

被引：52

作者：

Wu, XW

Hou, XL

Dai, LX

Tao, J

Cao, BX

Sun, J

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 04期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(01)00102-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel planar chiral N,O-[2,2]paracyclophane ligands were synthesised and applied as catalysts in the enantioselective addition of diethylzinc to aldehydes. The results indicate that the planar chirality of [2,2]paracyclophane, not the central chirality of the oxazoline, is the dominant stereocontrolling element. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：529 / 532

页数：4

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